Water

Pore (open) space within limestones might be preserved during deposition of carbonate sediment and can be formed during lithification by dissolution of grains and tectonic fracturing. These pore spaces can comprise up to 40% of the rock volume and may range in size from nanometres to kilometres, in the case of caves. In most cases, the pores are a few microns to a few millimetres in diameter, and sufficiently well connected that they can flow water. Recrystallization of limestone to form dolostone (Ca.Mg.CO3) can also create a well-connected network of crystalline pores.

phreatic cavern formed by groundwater

Cave formed by the flow of groundwater at the water table (phreatic cave), Longhorne Caverns, Texas

The high volume of pore space in carbonate rocks means that they form important aquifers in many countries, critical to the supply of freshwater. The groundwater in parts of the England comes from carbonate aquifers, for example around the ‘White Peak’ area of Derbyshire, north Yorkshire and the Mendip Hills. This gives us ‘hard’ water, which has high concentrations of calcium and magnesium bicarbonates that precipitates as a finely crystalline scale within pipes and domestic appliances. Water in these aquifers travels via underground caves and fractures before emerging at the surface as springs. The complex connectivity of caves and fractures in the subsurface can make it difficult to map the flow of groundwater in these aquifers, and water flow and discharge can also change quickly and dramatically after heavy rain.

Water

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